Synthesis and thermotropic phase behavior of four glycoglycerolipids.
نویسندگان
چکیده
Four glycoglycerolipids with different head groups have been synthesized and their physicochemical properties studied. The lengths of the head groups from a mono-saccharide to a trisaccharide, in addition to the anomeric stereochemistry for the smaller glycoglycerolipids, have been modified. The synthesis has been optimized to avoid glycerol epimerization and to allow up-scaling. The physicochemical properties of the glycoglycerolipids were studied and a strong de-mixing of the gel-phase, depending on the head-group, was observed.
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ورودعنوان ژورنال:
- Molecules
دوره 18 11 شماره
صفحات -
تاریخ انتشار 2013